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Xiong R, Arkhypchuk AI, Kovacs D, Orthaber A, Eszter Borbas K
Chem. Commun. (Camb.) 52 (58) 9056-9058 [2016-07-12; online 2016-02-10]
Directly linked hydroporphyrin (chlorin) dimers were accessed regioselectively from bromochlorins. Versatile 15-borylated chlorins were prepared in excellent yield via Miyaura borylation. Suzuki coupling yielded meso-meso-linked homo- and heterodimers, and meso-β-linked dimers. The photophysical and electrochemical properties of the dimers are reported.
PubMed 26859412
DOI 10.1039/c6cc00516k
Crossref 10.1039/c6cc00516k